为了探索水产养殖废水中难以降解的氨氮的最佳去除工艺,本实验采用电极生物膜法,在好氧区利用阳极碳棒电解产生的氧,在硝化细菌的作用下使氨氮转化为硝酸盐氮;在缺氧区利用阴极碳棒电解产生的氢,促进反硝化细菌实现反硝化脱氮。结果表明:温度过高或过低,对硝化和反硝化细菌的活性都有一定抑制;C/N比为1时,能实现氨氮与硝酸盐氮的同时去除;电流对硝化和反硝化处理效率有很大的促进作用;同时电流强度随氨氮负荷的增加而增大;水力停留时间越长,氨氮的去除率越高。
Abstract
In order explore the best removal process of refractory ammonia nitrogen in the aquaculture waste water, this experiment adopted biofilm-electrode process. Anode rod used in the aerobic zone produces oxygen, which turned ammonia nitrogen into nitrate nitrogen with the help of nitrobacteria. And Cathode carbon in the anoxic zone electrolyzed hydrogen, which contributed to the realizing denitrification of denitrifying bacteria. The results showed that: too high or too low temperature restrained the activity of nitrifying bacteria and denitrifying bacteria. When the C/N rate was 1, the ammonia nitrogen and nitrate nitrogen could be removed at the same time. The current played a great role in promoting the efficiency of nitrification and denitrification process. And the current intensity increased with the increase of ammonia nitrogen load. The removal rates of ammonia nitrogen would be improved with greater hydraulic power.
关键词
电极生物膜法; 养殖废水; 氨氮; 反硝化; 水力停留时间
{{custom_keyword}} /
Key words
biofilm-electrode reactor; aquaculture wastewater; ammonia; denitrification; HRT
{{custom_keyword}} /
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] 蔡继晗,沈奇宇,郑向勇,等.氨氮污染水产养殖的危害及处理技术研究进展[J].浙江海洋学院学报:自然科学版,2010,29(2)167-172.
[2] Sakakibara Y, Flora J R V, Suidan M T, et al. Modeling of electro chemically activated denitrifying biofilms[J].Wat.Res.,1994,28(5): 1077-1086.
[3] Sakakibara Y, Nakayama T. A novel multi-electrode system for electrolytic and biological water treatments electric charge transfer and application to denitrification[J].Wat.Res.,2001,35(3):768-778.
[4] Sakakibara Y, Kroda M. Electric prompting and control of denitrification. Biotcch[J].Bjoeng.,1993,42:535-537.
[5] 庞朝晖,刘迎云,彭彩红,等.电极生物膜处理渗滤液中硝酸盐氮的实验研究[J].中国农村水利水电,2007,10:40-42.
[6] 庞朝晖.电极-生物膜法处理渗滤液中硝酸盐氮的实验研究[D].湖南:南华大学,2007:66-67.
[7] 俞汉青,顾国维.生物膜反应器挂膜方法的研究[J].中国给水排水, 1992,8(3):13-17.
[8] 鲍立宁,黄怀显,黄勇,等.电极生物膜工艺去除微污染源水中氨氮的研究[J].中国给水排水,2008,15:28-31.
[9] 庞朝晖,刘迎云,刘文碧.温度和电流对电极生物膜反硝化效果的影响[J].南华大学学报:自然科学版,2007,21:60-63.
[10] 庞朝晖,张敏,张帆,等.电极生物膜处理地下水中硝酸盐氮的实验研究[J].水处理技术,2010,5:93-95.
[11] 徐亚同.废水反硝化除氮[J].上海环境科学 1994,13:8-12.
[12] Collivignare C, Bertanza G. Simultaneous NitrificationDenitrification Process in Activated sludge Plants performance and Applicability[J].Wat.Res,1999,40(45):187-194.
[13] 高景峰,彭永臻,王淑莹,等.SBR法去除有机物、硝化和反硝化过程中 pH变化规律[J].环境工程,2001,19:21-24.
[14] 郑平,胡宝兰.厌氧氨氧化菌混培物生长及代谢动力学研究[J].生物工程学报,2001,17(2):193-198.
[15] 胡海燕.水产养殖废水氨氮处理研究[D].山东:中国海洋大学, 2007:1-2.
{{custom_fnGroup.title_cn}}
脚注
{{custom_fn.content}}