森美思纳米材料在Cd、Cu复合污染稻田施用效果研究

方克明, 肖欣, 叶医群, 钟国民, 朱安繁, 周丽芳, 王美玲, 王福林, 洪讯诚

农学学报. 2020, 10(6): 46-51

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农学学报 ›› 2020, Vol. 10 ›› Issue (6) : 46-51. DOI: 10.11924/j.issn.1000-6850.cjas19040001
土壤肥料/资源环境/生态

森美思纳米材料在Cd、Cu复合污染稻田施用效果研究

作者信息 +

Application Effects of SAMMNS Nanometer Material in Paddy Fields of Cd & Cu Composite Pollution

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History +

摘要

森美思(SAMMNS)是一种应用于“三废”污染治理的纳米多孔复合材料。为验证森美思纳米材料在稻田重金属Cd污染的治理效果,在土壤Cd、Cu复污染稻田开展了森美思纳米材料不同用量的正规田间试验。试验显示,施用化肥会使土壤酸化,使糙米Cd量降低和糙米Cu量上升。水稻对Cd具有很强的富集效应,对Cu只是一般吸收。结果表明,施用森美思纳米材料能显著提升土壤pH值,有效降低土壤有效Cd量和糙米Cd量,土壤有效Cd量与糙米Cd量之间存在正相关性。施用3000 kg/hm2森美思纳米材料糙米Cd量均值比空白对照和施肥对照分别下降40.54%和30.62%,处理差异达到显著水平。施用森美思纳米材料对降低糙米Cu量也有一定作用,但不及降低糙米Cd量效果。施用森美思纳米材料对水稻有小幅增产效果。

Abstract

SAMMNS is a kind of nanometer material used in the treatment of “three wastes” pollution control. To verify the application effects of SAMMNS nanometer material on heavy metal Cd contaminated paddy fields, field experiments with different amounts of SAMMNS nanometer material were carried out in paddy fields with composite pollution by Cd and Cu. The experiments showed that the application of chemical fertilizers could acidify the soil, reduce the amount of Cd and increase the amount of Cu in brown rice. Rice had a strong enrichment effect on Cd, but only general absorption on Cu. The results showed that the application of SAMMNS nanometer material could significantly increase the pH value of soil and effectively reduce the effective Cd content in soil and that in brown rice, and there was a positive correlation between the effective Cd content in soil and that in brown rice. Compared with blank control and fertilization control, the mean value of Cd in brown rice with 3000 kg/hm2 SAMMNS nanometer material decreased by 40.54% and 30.62%, respectively, and the difference of the treatment reached a significant level. The application of SAMMNS nanometer material also had a certain effect on reducing the amount of Cu in brown rice, but it is not as effective as reducing the amount of Cd in brown rice. The application of SAMMNS nanometer material has a small yield increase effect on rice.

关键词

森美思 / 纳米材料 / Cd、Cu复合污染稻田 / 改良效果

Key words

SAMMNS / Nanometer Material / Paddy Fields of Cd & Cu Composite Pollution / Improvement Effect

引用本文

导出引用
方克明 , 肖欣 , 叶医群 , 钟国民 , 朱安繁 , 周丽芳 , 王美玲 , 王福林 , 洪讯诚. 森美思纳米材料在Cd、Cu复合污染稻田施用效果研究. 农学学报. 2020, 10(6): 46-51 https://doi.org/10.11924/j.issn.1000-6850.cjas19040001
Fang Keming , Xiao Xin , Ye Yiqun , Zhong Guomin , Zhu Anfan , Zhou Lifang , Wang Meiling , Wang Fulin , Hong Xuncheng. Application Effects of SAMMNS Nanometer Material in Paddy Fields of Cd & Cu Composite Pollution. Journal of Agriculture. 2020, 10(6): 46-51 https://doi.org/10.11924/j.issn.1000-6850.cjas19040001

参考文献

[1]
何念祖, 孟赐福. 植物营养原理[M] 上海: 上海科学技术出版社, 1987: 354.
[2]
汪鹏, 王静, 陈宏坪, 等. 我国稻田系统镉污染风险与阻控[J]. 农业环境科学学报, 2018,37(7):1409-1417.
[3]
雷鸣, 曾敏, 王利红, 等. 湖南市场和污染区稻米中As、Pb、Cd污染及其健康风险评价[J]. 环境科学学报, 2010,30(11):2314-2320.
为了更好地了解和评价湖南大米中As、Pb和Cd含量及其对人体的健康影响,在对湖南矿区和冶炼区水稻土壤重金属污染调查的基础上,分别以湖南各地市场大米和污染区当地生产的稻谷样品为例,对其进行重金属含量分析及对人体的健康风险评价.结果表明,湖南各地市场大米样品中As、Pb和Cd的平均含量分别是0.20、0.20和0.28mg·kg-1,其中,衡阳市场大米中的As、Pb和Cd含量最高,其次是株洲和湘潭市场的大米.污染区稻谷中As、Pb和Cd含量分布均为:谷壳>糙米>精米,污染区精米中As、Pb和Cd的含量分别是0.24、0.21和0.65mg·kg-1,其中,来自衡阳常宁市水口山铅/锌矿区的稻谷样品中的As、Pb和Cd含量最高,其次是株洲清水塘冶炼区和湘潭锰矿区的稻谷.与市场大米样品相比,污染区精米中As、Pb和Cd的平均含量比市场大米样品高.无论是市场大米样品,还是从污染区稻田采集的稻米,均以衡阳地区稻米中的As、Pb和Cd污染最为严重,其次为株洲和湘潭地区.在As、Pb和Cd的健康风险评价中,Cd是湖南各地稻米中影响人体健康的主要因子,株洲和湘潭的Cd污染区达到90%以上,其次是As和Pb.
[4]
何凤鹏, 谷雨, 冯光辉, 等. 不同类型土壤调理剂对土壤—水稻系统重金属含量的影响[J] . 湖南农业科学, 2016(5):31-34.
[5]
谢运河, 黄伯军, 纪雄辉, 等. 镉污染稻田专用土壤调理剂修复效果评价[J] . 湖南农业科学, 2017(12):31-35.
[6]
樊霆, 叶文玲, 陈海燕, 等. 农田土壤重金属污染状况及修复技术研究[J]. 生态环境学报, 2013,22(10):1727-1736.
[7]
生态环境部南京环境科学研究所, 中国科学院南京土壤研究所, 中国农业科学院农业资源与农业区划研究所, 等. GB 15618—2018,土壤环境质量农用地土壤污染风险管控标准(试行)[S]. 2018.
[8]
江民锦, 胡佳琴, 司卫静. 江西德兴铜矿矿区内铜富集植物的调查及筛选[J]. 江苏农业科学, 2013,41(7):357-361.
[9]
中国疾病预防控制中心营养与食品安全所, 中国食品发酵工业研究院, 中国农业科学研究院农业质量与标准技术研究所, 等. GB 2762—2017,食品国家安全标准食品中污染物限量[S]. 北京: 中国标准出版社出版, 2017: 4-5
[10]
国务院. 土壤污染防治行动计划[Z],国发[2016]31号.2016-05-28发布.
[11]
龚海军, 刘昭兵, 纪雄辉, 等. 新型土壤改良剂对水稻吸收Cd、Pb累积的影响初探[J] . 湖南农业科学, 2010(5):50-53.
在盆栽条件下研究了一种新型土壤改良剂(商品名:农大夫-地保2号,又名土壤还原素)对两种污染土壤(潮泥田和红黄泥)水稻吸收累积Cd、Pb的影响.结果表明,施用土壤改良剂能显著提高潮泥田和红黄泥的土壤pH值,降低土壤有效态Cd、Pb及水稻糙米Cd、Pb含量.当土壤改良剂施用量达到8 g/kg时,两种土壤的pH值均显著高于对照(H-0).当土壤改良剂施用量达到4 g/kg时,潮泥田土壤有效态Cd含量低于对照30.8%(P<0.05);当其施用量增至8 g/kg时,土壤有效态Pb含量比对照降低21.9%(P<0.05),同时水稻糙米Cd、Pb含量比对照降低18.4%(P<0.05)和20.3%(P<0.05).当土壤改良剂施用量达到8 g/kg时,红黄泥土壤有效态Cd、Pb分别低于对照30.7%(P<0.05)和24.4%(P<0.05),而其水稻糙米Cd、Pb含量在土壤改良剂施用量为4 g/kg时降幅达22.8%(P<0.05)和24.2%(P<0.05).综合分析认为,施土壤改良剂能显著降低污染土壤上水稻糙米的Cd、Pb累积,其效果与土壤改良剂用量、土壤pH值及土壤Cd、Pb含量有关,可能对酸性土壤更有效.
Abstract:
Pot experiments were conducted to study the effects of a soil amendment(trade name:Nong Dafu-Di Bao 2,also known as soil reducing agent)on absorption and accumulation of Cd and Pb by rice in polluted reddish yeHow paddy soil(RYPS)and alluvial loamy paddy soil(ALPS).The results showed that applying soil reducing agent could remarkably improve the PH values of RYPS and ALPS,and decrease the contents of available Cd and Pb in soil and Cd and Pb in brown rice.When applying amount of soil reducing agent reached 8 g/kg.the PH values of both kinds of soil were significantly higher than that of control(H-O).When applying amount of soil reducing agent was 4 g/kg,the available Cd content in ALPS was 30.8%(P<0.05)lower than that of control,and the contents of Cd and Pb in brown rice from RYPS decreased by 22.8%(P<0.05)and 24.2%(P<0.05),respectively.When applying amount of soil reducing agent reached 8g/kg,the available Pb content in ALPS was 21.9% lower than that of control(P<0.05),the contend of Cd and Pb in brown rice from ALPS were 18.4%(P<0.05)and 20.3%(P<0.05)lower than that of control,respectively,and the available contents of Cd and Pb in RYPS were 30.7% (P<0.05)and 24.4% lower than that of control,respectively.It might be concluded that the application of soil reducing agent can significantly reduce the accumulation of Cd and Pb in brown rice from polluted soft;the reducing effect related to the applying amount of soil reducing agent,the pH value of soil and the contents of Cd and Pb in soil.and it might be more effective to acid soil.
[12]
石小娟, 刘玉清, 易悦, 等. 3种含磷材料修复铜镉复合污染土壤的研究[J] . 湖南农业科学, 2015(4):116-118,121.
[13]
田发祥, 谢运河, 纪雄辉. 土壤重金属污染修复剂在镉污染稻田中的应用效果[J] . 湖南农业科学, 2015(2):95-98.
[14]
奉启云, 李红涛, 奉向东, 等. 森美思土壤调理剂对Cd污染稻田修复效果研究[J]. 有色冶金设计与研究 2018(5):15-19.
[15]
李伯欣, 杨玉环, 罗顺辉, 等. 森美思土壤调理剂对镉污染稻田改良的影响研究[J] 南方农业, 2018(23):185-187.
[16]
李心, 林大松, 刘岩, 等, 不同土壤调理剂对镉污染稻田控镉效应研究[J] 农业环境科学学报, 2018,37(7):1511-1520.
[17]
方克明, 钟国民, 周丽芳, 等. 石灰在酸性稻田的施用效果[J] . 中国土壤与肥料, 2017(5):105-109.
[18]
詹杰, 魏树和, 牛荣成. 我国稻田土壤镉污染现状及安全生产新措施[J]. 农业环境科学学报, 2012,31(7):1257-1263.
[19]
邵赛男, 徐君, 顾万帆, 等. 不同施肥方式对土壤重金属累积的影响[J]. 浙江农业科学, 2017,58(1):180-182.
[20]
任荣福, 葛送来, 解怀生, 等. 重金属铬和镉在土壤与稻米中的分布及其相关性[J] . 浙江农业科学, 2011(1):138-141,170.
[21]
吴迎奔, 刘剑波, 贺月林, 等. 介孔硅纳米材料颗粒对水稻镉吸收的影响[J] . 中国土壤与肥料, 2016(2):145-148
[22]
刘大锷, 郭明选, 高汉清, 等. 施用生石灰对镉污染酸性土壤中水稻镉积累的影响[J] . 湖南农业科学, 2016(12):24-26.
[23]
郝汉舟, 靳孟贵, 李瑞敏, 等. 耕地土壤铜、镉、锌形态及生物有效性研究[J]. 生态环境学报, 2010,19(1):92-96.
[24]
关天霞, 何红波, 张旭东, 等. 土壤重金属元素形态分析方法及形态分布的影响[J]. 土壤通报, 2011,42(2):503-512.
[25]
吴琼, 赵同科, 邹国元, 等. 北京东南郊农田土壤重金属含量与环境质量评价[J] . 中国土壤与肥料, 2016(1):7-12.
[26]
肖蓉, 罗容珺, 付祖姣, 等. 几种矿质材料对镉吸附性能的研究[J] . 湖南农业科学, 2016(9):41-44.

基金

景德镇市科技计划项目“农田稻米镉污染防控技术研究”(ny20175416)

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